Conceptual Question on Heisenberg Uncertainty Principle. #2

 QUESTION:

The uncertainty in an electron’s position is 10.0\rm \ pm.
a) Find the minimum uncertainty in its momentum.
b) Find the minimum uncertainty in its velocity.
c) What will be the kinetic energy of the electron if the momentum is equal to the uncertainty in momentum?

 SOLUTION:

Let’s suppose:

  • m is the mass of the particle,
  • \Delta x is the uncertainty in position, 
  • \Delta P is the uncertainty in momentum, and
  • \Delta V is the uncertainty in velocity.

Given:

  • \Delta x = 10.0 \rm \ pm = 10.0 \times 10^{-12}\rm \ m

To find:

  • \Delta P, and
  • \Delta V

We know the values:

  • h = 6.626 \times 10^{ -34}\rm \  J \cdot s

  • m_e = 9.11\times 10^{-31}\rm \ kg

From the Heisenberg uncertainty principle, the uncertainty in position and the uncertainty in momentum are related by an equation;

\begin{aligned}\Delta x \times \Delta P &\geq \dfrac{h}{4\pi}\\\Rightarrow \Delta P &\geq \dfrac{h}{4\pi\Delta x}\\ &= \dfrac{6.626 \times 10^{ -34}\rm \ J \cdot s}{4\pi \times (10.0 \times 10^{-12}\rm \ m)}\\&= 5.27 \times 10^{ -24} \rm \  kg \cdot m/s\\\end{aligned}

Therefore, the minimum uncertainty in the particle’s momentum is

\begin{aligned}\Delta P &= 5.27 \times 10^{ -24} \rm \ kg \cdot m/s\\\end{aligned}

The uncertainty in the velocity and the uncertainty in momentum are related as;

\begin{aligned}\Delta P &= m \Delta V\\\end{aligned}

So, the minimum uncertainty in the particle’s velocity is calculated as

\begin{aligned}\Delta V &= \dfrac{\Delta P}{m_e}\\&= \dfrac{5.27 \times 10^{ -24} \rm \ kg \cdot m/s }{9.11\times 10^{-31}\rm \ kg }\\&= 5.78 \times 10^{6}\rm \ m/s\\\end{aligned}

Therefore, the minimum uncertainty in the electron’s velocity is

\begin{aligned}\Delta V &= 5.32 \times 10^{6}\rm \ m/s \\\end{aligned}

Given the momentum of the electron is equal to its minimum uncertainty. That is P = \Delta P

So, the kinetic energy of the electron when momentum is equal to its minimum uncertainty is given by

\begin{aligned}K.E. &= \dfrac{P^2}{2m_e}\\&= \dfrac{( \Delta P)^2}{2m_e}\\&= \dfrac{(5.27 \times 10^{ -24} \rm \ kg \cdot m/s)^2}{2 \times (9.11\times 10^{-31}\rm \ kg )}\\&= 1.52 \times 10^{ -17} \rm \ J\\\end{aligned}

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