QUESTION:
The uncertainty in an electron’s position is 10.0\rm \ pm.
a) Find the minimum uncertainty in its momentum.
b) Find the minimum uncertainty in its velocity.
c) What will be the kinetic energy of the electron if the momentum is equal to the uncertainty in momentum?
SOLUTION:
Let’s suppose:
- m is the mass of the particle,
- \Delta x is the uncertainty in position,
- \Delta P is the uncertainty in momentum, and
- \Delta V is the uncertainty in velocity.
Given:
\Delta x = 10.0 \rm \ pm = 10.0 \times 10^{-12}\rm \ m
To find:
- \Delta P, and
- \Delta V
We know the values:
h = 6.626 \times 10^{ -34}\rm \ J \cdot s
m_e = 9.11\times 10^{-31}\rm \ kg
From the Heisenberg uncertainty principle, the uncertainty in position and the uncertainty in momentum are related by an equation;
\begin{aligned}\Delta x \times \Delta P &\geq \dfrac{h}{4\pi}\\\Rightarrow \Delta P &\geq \dfrac{h}{4\pi\Delta x}\\ &= \dfrac{6.626 \times 10^{ -34}\rm \ J \cdot s}{4\pi \times (10.0 \times 10^{-12}\rm \ m)}\\&= 5.27 \times 10^{ -24} \rm \ kg \cdot m/s\\\end{aligned}
Therefore, the minimum uncertainty in the particle’s momentum is
\begin{aligned}\Delta P &= 5.27 \times 10^{ -24} \rm \ kg \cdot m/s\\\end{aligned}
The uncertainty in the velocity and the uncertainty in momentum are related as;
\begin{aligned}\Delta P &= m \Delta V\\\end{aligned}
So, the minimum uncertainty in the particle’s velocity is calculated as
\begin{aligned}\Delta V &= \dfrac{\Delta P}{m_e}\\&= \dfrac{5.27 \times 10^{ -24} \rm \ kg \cdot m/s }{9.11\times 10^{-31}\rm \ kg }\\&= 5.78 \times 10^{6}\rm \ m/s\\\end{aligned}
Therefore, the minimum uncertainty in the electron’s velocity is
\begin{aligned}\Delta V &= 5.32 \times 10^{6}\rm \ m/s \\\end{aligned}
Given the momentum of the electron is equal to its minimum uncertainty. That is P = \Delta P
So, the kinetic energy of the electron when momentum is equal to its minimum uncertainty is given by
\begin{aligned}K.E. &= \dfrac{P^2}{2m_e}\\&= \dfrac{( \Delta P)^2}{2m_e}\\&= \dfrac{(5.27 \times 10^{ -24} \rm \ kg \cdot m/s)^2}{2 \times (9.11\times 10^{-31}\rm \ kg )}\\&= 1.52 \times 10^{ -17} \rm \ J\\\end{aligned}
Similar Problems based on Heisenberg’s Uncertainty Principle
The location of a particle is measured with an uncertainty of 2.145\rm \ nm . a) What will be the resulting minimum uncertainty in the particle’s momentum? b) If the mass of the particle is 4.734 \times 10^{ -27}\rm \ kg then what will be the minimum uncertainty in the velocity measurement?
A particle’s energy is measured with an uncertainty of 1.1 \times 10^{ -3}\rm \ eV. What will be the smallest possible uncertainty in our knowledge of when the particle had the given uncertainty of energy?
a) If an electron’s position can be measured to a precision of 2.0 \times 10^{ -8} \rm \ m, what will be the uncertainty in its momentum? b) If its momentum is equal to its uncertainty then what will be the electron’s wavelength?
Suppose the speed of electrons present in the first shell of an atom is 50% of the speed of light. If the uncertainty in velocity is 1000\rm \ m/s, what is the uncertainty in the position of this electron?